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Photocatalyst sheets: from one SrTiO₃ particle to a 100 m² hydrogen farm

A survey-map graphical abstract of particulate photocatalysts for overall water splitting: an aerial view of a 100 m² array of panel reactors, with map pins leading to the aluminium-doped SrTiO₃ particle (cocatalysts for hydrogen and oxygen on different facets, 96% external quantum efficiency in the UV), the photocatalyst-sheet panel, and the polyimide membrane that recovers hydrogen safely from the mixed gas.

Updated 4 cited papers221 editable layers

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At a glance

Category
Graphical abstracts
Method
Graphical abstract
Starting materials
Aluminium-doped SrTiO₃ powder with Rh/Cr₂O₃ and CoOOH cocatalysts
Product
Hydrogen recovered from water and sunlight on a 100 m² panel array
Key result
EQE up to 96% at 350–360 nm (Takata et al. 2020); STH 0.76% on 100 m² (Nishiyama et al. 2021); STH 1.1% for Z-scheme sheets (Wang et al. 2016)
Figure
1920 × 1080 px (16:9), 221 editable layers, 1 generated objects

Step by step

  1. A · The particleAl-doped SrTiO₃ with Rh/Cr₂O₃ for H₂ and CoOOH for O₂ on different facets: external quantum efficiency up to 96% at 350–360 nm, against typically < 10% before (Takata et al. 2020)
  2. B · The panelPowder fixed as sheets in panel reactors; light makes electron–hole pairs that separate and react at the surface (Wang & Domen 2020); the H₂/O₂ product leaves as one moist mixture (Nishiyama et al. 2021); sheets of two photocatalysts on gold reached 1.1% STH (Wang et al. 2016)
  3. C · The separatorA commercial polyimide membrane recovers H₂ from the moist H₂/O₂ mixture; the system survived intentional ignition of the recovered hydrogen (Nishiyama et al. 2021)
  4. D · The array100 m² of panel reactors ran safely for several months, with a maximum STH of 0.76% (Nishiyama et al. 2021)

Uses

  • Graphical abstracts on photocatalytic water splitting and solar hydrogen
  • Talks on scaling up particulate photocatalysts
  • Teaching cocatalysts and charge separation

Papers this template follows

  1. Takata et al., “Photocatalytic water splitting with a quantum efficiency of almost unity”, Nature 2020. doi:10.1038/s41586-020-2278-9primary
  2. Nishiyama et al., “Photocatalytic solar hydrogen production from water on a 100-m² scale”, Nature 2021. doi:10.1038/s41586-021-03907-3primary
  3. Wang et al., “Scalable water splitting on particulate photocatalyst sheets with a solar-to-hydrogen energy conversion efficiency exceeding 1%”, Nat. Mater. 2016. doi:10.1038/nmat4589primary
  4. Wang & Domen, “Particulate photocatalysts for light-driven water splitting: mechanisms, challenges, and design strategies”, Chem. Rev. 2020. doi:10.1021/acs.chemrev.9b00201review

Drawn by LabCanvas after Takata et al., Nature 2020 (doi:10.1038/s41586-020-2278-9); Nishiyama et al., Nature 2021 (doi:10.1038/s41586-021-03907-3); Wang et al., Nat. Mater. 2016 (doi:10.1038/nmat4589) and Wang & Domen, Chem. Rev. 2020 (doi:10.1021/acs.chemrev.9b00201).

How templates are written and checked: editorial guidelines.

Questions

What does the “Photocatalyst sheets: from one SrTiO₃ particle to a 100 m² hydrogen farm” template show?

A survey-map graphical abstract of particulate photocatalysts for overall water splitting: an aerial view of a 100 m² array of panel reactors, with map pins leading to the aluminium-doped SrTiO₃ particle (cocatalysts for hydrogen and oxygen on different facets, 96% external quantum efficiency in the UV), the photocatalyst-sheet panel, and the polyimide membrane that recovers hydrogen safely from the mixed gas.

What are the steps shown in “Photocatalyst sheets: from one SrTiO₃ particle to a 100 m² hydrogen farm”?

1. A · The particle: Al-doped SrTiO₃ with Rh/Cr₂O₃ for H₂ and CoOOH for O₂ on different facets: external quantum efficiency up to 96% at 350–360 nm, against typically < 10% before (Takata et al. 2020). 2. B · The panel: Powder fixed as sheets in panel reactors; light makes electron–hole pairs that separate and react at the surface (Wang & Domen 2020); the H₂/O₂ product leaves as one moist mixture (Nishiyama et al. 2021); sheets of two photocatalysts on gold reached 1.1% STH (Wang et al. 2016). 3. C · The separator: A commercial polyimide membrane recovers H₂ from the moist H₂/O₂ mixture; the system survived intentional ignition of the recovered hydrogen (Nishiyama et al. 2021). 4. D · The array: 100 m² of panel reactors ran safely for several months, with a maximum STH of 0.76% (Nishiyama et al. 2021).

What are the starting materials and the product?

Starting materials: Aluminium-doped SrTiO₃ powder with Rh/Cr₂O₃ and CoOOH cocatalysts. Product: Hydrogen recovered from water and sunlight on a 100 m² panel array.

Which papers is “Photocatalyst sheets: from one SrTiO₃ particle to a 100 m² hydrogen farm” based on?

Takata et al., “Photocatalytic water splitting with a quantum efficiency of almost unity”, Nature 2020 (doi:10.1038/s41586-020-2278-9); Nishiyama et al., “Photocatalytic solar hydrogen production from water on a 100-m² scale”, Nature 2021 (doi:10.1038/s41586-021-03907-3); Wang et al., “Scalable water splitting on particulate photocatalyst sheets with a solar-to-hydrogen energy conversion efficiency exceeding 1%”, Nat. Mater. 2016 (doi:10.1038/nmat4589); Wang & Domen, “Particulate photocatalysts for light-driven water splitting: mechanisms, challenges, and design strategies”, Chem. Rev. 2020 (doi:10.1021/acs.chemrev.9b00201).

Can I edit the “Photocatalyst sheets: from one SrTiO₃ particle to a 100 m² hydrogen farm” template?

Yes. Open it in the LabCanvas editor: all 221 layers are editable, including 1 generated objects (structures, plots, equipment) with their own settings. Change the text, colours and layout, then export PNG, TIFF, SVG or PDF.

Do I need an account to use this template?

Not to view it here. To open and edit it, sign in to LabCanvas or create a free account (the free plan keeps up to 3 designs). Downloading the figure is part of LabCanvas Pro (US$19 a month or US$199 a year).

photocatalysisoverall water splittingsolar hydrogenparticulate photocatalystphotocatalyst sheetSrTiO3:Alstrontium titanatecocatalystRh/Cr2O3CoOOHquantum efficiencypanel reactorgas separationpolyimide membranegraphical abstract3D model

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