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Tough hydrogels: sacrificial bonds that break so the gel does not

A radial graphical abstract on tough hydrogels: a live 3D water-swollen polymer network at the hub, with four satellites on its structure, the sacrificial-bond mechanism, the numbers and the uses. Ordinary gels are brittle; double-network and ionic–covalent hybrid gels add weak bonds that break first and dissipate energy, lifting the fracture energy from about 10 to about 9,000 J m⁻².

Updated 5 cited papers89 editable layers

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At a glance

Category
Materials graphical abstracts
Method
Graphical abstract
Starting materials
A water-swollen polymer network, about 90% water
Product
A tough, highly stretchable hydrogel
Key result
Alginate–polyacrylamide: about 90% water, stretch beyond 20 (17 with a notch), fracture energy about 9,000 J m⁻², against about 10 J m⁻² for most hydrogels (Sun et al., Nature 2012)
Figure
1920 × 1080 px (16:9), 89 editable layers, 5 generated objects

Step by step

  1. Network structureTwo interlaced networks: alginate held by Ca²⁺ ionic cross-links and polyacrylamide held by covalent cross-links, about 90% water
  2. Sacrificial bondsUnder stretch the weak bonds (the brittle first network, or the ionic cross-links) break first and dissipate energy while the stretchy network bridges the crack; ionic cross-links can re-zip
  3. The numbersFracture energy about 10 J m⁻² for most hydrogels, about 1,000 for double-network gels and cartilage, about 9,000 for alginate–polyacrylamide, which stretches beyond 20 times its length
  4. UsesHydraulic soft actuators and robots, scaffolds and artificial soft tissues, tough adhesives for wet surfaces

Uses

  • Soft actuators and robots
  • Tissue-engineering scaffolds and artificial cartilage
  • Tough adhesives for wet tissue
  • Teaching soft-matter toughening

Papers this template follows

  1. Sun et al., “Highly stretchable and tough hydrogels”, Nature 2012. doi:10.1038/nature11409primary
  2. Nonoyama & Gong, “Double-network hydrogel and its potential biomedical application: A review”, Proc. Inst. Mech. Eng. H 2015. doi:10.1177/0954411915606935review
  3. Nonoyama & Gong, “Tough Double Network Hydrogel and Its Biomedical Applications”, Annu. Rev. Chem. Biomol. Eng. 2021. doi:10.1146/annurev-chembioeng-101220-080338review
  4. Yuk et al., “Hydraulic hydrogel actuators and robots optically and sonically camouflaged in water”, Nat. Commun. 2017. doi:10.1038/ncomms14230further reading
  5. Li et al., “Tough adhesives for diverse wet surfaces”, Science 2017. doi:10.1126/science.aah6362further reading

Drawn by LabCanvas after Sun et al., Nature 2012 (doi:10.1038/nature11409); Nonoyama & Gong, Proc. Inst. Mech. Eng. H 2015 (doi:10.1177/0954411915606935); Yuk et al., Nat. Commun. 2017 (doi:10.1038/ncomms14230) and Li et al., Science 2017 (doi:10.1126/science.aah6362).

How templates are written and checked: editorial guidelines.

Questions

What does the “Tough hydrogels: sacrificial bonds that break so the gel does not” template show?

A radial graphical abstract on tough hydrogels: a live 3D water-swollen polymer network at the hub, with four satellites on its structure, the sacrificial-bond mechanism, the numbers and the uses. Ordinary gels are brittle; double-network and ionic–covalent hybrid gels add weak bonds that break first and dissipate energy, lifting the fracture energy from about 10 to about 9,000 J m⁻².

What are the steps shown in “Tough hydrogels: sacrificial bonds that break so the gel does not”?

1. Network structure: Two interlaced networks: alginate held by Ca²⁺ ionic cross-links and polyacrylamide held by covalent cross-links, about 90% water. 2. Sacrificial bonds: Under stretch the weak bonds (the brittle first network, or the ionic cross-links) break first and dissipate energy while the stretchy network bridges the crack; ionic cross-links can re-zip. 3. The numbers: Fracture energy about 10 J m⁻² for most hydrogels, about 1,000 for double-network gels and cartilage, about 9,000 for alginate–polyacrylamide, which stretches beyond 20 times its length. 4. Uses: Hydraulic soft actuators and robots, scaffolds and artificial soft tissues, tough adhesives for wet surfaces.

What are the starting materials and the product?

Starting materials: A water-swollen polymer network, about 90% water. Product: A tough, highly stretchable hydrogel.

Which papers is “Tough hydrogels: sacrificial bonds that break so the gel does not” based on?

Sun et al., “Highly stretchable and tough hydrogels”, Nature 2012 (doi:10.1038/nature11409); Nonoyama & Gong, “Double-network hydrogel and its potential biomedical application: A review”, Proc. Inst. Mech. Eng. H 2015 (doi:10.1177/0954411915606935); Nonoyama & Gong, “Tough Double Network Hydrogel and Its Biomedical Applications”, Annu. Rev. Chem. Biomol. Eng. 2021 (doi:10.1146/annurev-chembioeng-101220-080338); Yuk et al., “Hydraulic hydrogel actuators and robots optically and sonically camouflaged in water”, Nat. Commun. 2017 (doi:10.1038/ncomms14230); Li et al., “Tough adhesives for diverse wet surfaces”, Science 2017 (doi:10.1126/science.aah6362).

Can I edit the “Tough hydrogels: sacrificial bonds that break so the gel does not” template?

Yes. Open it in the LabCanvas editor: all 89 layers are editable, including 5 generated objects (structures, plots, equipment) with their own settings. Change the text, colours and layout, then export PNG, TIFF, SVG or PDF.

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Not to view it here. To open and edit it, sign in to LabCanvas or create a free account (the free plan keeps up to 3 designs). Downloading the figure is part of LabCanvas Pro (US$19 a month or US$199 a year).

graphical abstracttough hydrogelhydrogelsacrificial bondsdouble networkDN gelalginate–polyacrylamideionic cross-linksenergy dissipationfracture energysoft matterpolymer networksoft roboticstissue adhesiveradial layoutlive 3D

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